Wednesday, July 11, 2012

Wife of Tetra Pak heir found dead in London

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Source: http://news.yahoo.com/wife-tetra-pak-heir-feared-dead-london-192815686.html

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Wall Street slips on global growth concerns

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Source: http://news.yahoo.com/wall-street-set-weaker-start-085458545--finance.html

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Waste to watts: Improving microbial fuel cells

ScienceDaily (July 10, 2012) ? Some of the planet's tiniest inhabitants may help address two of society's biggest environmental challenges: how to deal with the vast quantities of organic waste produced and where to find clean, renewable energy.

According to C?sar Torres and Sudeep Popat, researchers at Arizona State University's Biodesign Institute, certain kinds of bacteria are adept at converting waste into useful energy. These microorganisms are presently being applied to the task, through an innovative technology known as a microbial fuel cell or MFC.

As Torres explains, "the great advantage of the microbial fuel cell is the direct conversion of organic waste into electricity. " In the future, MFC's may be linked to municipal waste streams or sources of agricultural and animal waste, providing a sustainable system for waste treatment and energy production.

To scale up the technology however, improvements in efficiency will be required. "My particular focus is to understand at a fundamental level how anode respiring bacteria transfer electrons from their cells onto an electrode," Popat says, "as well as to design new systems that are both economical and efficient."

The group was able to demonstrate that significant loss in MFC efficiency was due to reactions occurring at the fuel cell's cathode. By modifying materials used in the cathode, as well as adjusting pH levels, they were able to improve cathode performance.

The group's research results appeared recently in the journal ChemSusChem in a special issue devoted to MFC technology.

Torres and Popat work in Biodesign's Swette Center for Environmental Biotechnology, directed by ASU Regents' professor Bruce Rittmann -- a co-author of the current study. Environmental biotechnology is a rapidly developing discipline in which disparate fields including microbiology, bioinformatics, chemistry, genomics, materials science, and engineering join together to harness biological entities -- including bacteria -- for the purpose of helping society.

Two chief areas of environmental biotechnology are bioremediation, or the clean up of environmental contaminants, and the production of clean energy. As the authors note, an MFC can perform double duty, targeting electrons from waste streams and converting them into useful energy.

An MFC is a unique kind of battery -- part electrochemical cell, part biological reactor. Typically, it contains two electrodes, separated by an ion exchange membrane. On the anode side, bacteria grow and proliferate, forming a dense cell aggregate known as a biofilm that adheres to the MFC's anode. In the course of their microbial metabolism, the bacteria act as catalysts for converting the organic substrate into CO2, protons, and electrons.

Under natural conditions, many bacteria use oxygen as a final electron acceptor to produce water, but in the oxygen-free environment of the MFC, specialized bacteria that send the electrons to an insoluble electron acceptor, namely the MFC's anode, dominate.

The anode-respiring bacteria are able to oxidize organic pollutants, such as those found in waste streams, and transfer the electrons to the anode. The scavenged electrons then flow through an electrical circuit, terminating at the MFC's cathode, thus generating electricity. Ions are transported through the fuel cell's ion membrane, to maintain electroneutrality, although the membrane is often excluded.

In an effort to refine the technology and address losses in MFC efficiency, the group looked at the oxygen reduction reaction at the MFC cathode. While it had earlier been speculated that efficiency loss at the cathode was due to a low availability of protons, the new research showed instead that the transport of hydroxide ions (OH-) away from the catalyst layer of the cathode and into the surrounding liquid largely governed cathode potential losses in the device.

"We found that the cathodes were limiting the power densities we can produce in these MFCs," Popat says. "This is very surprising because, in chemical fuel cells, the same catalyst allows much greater power densities."

A key to the disparity lies in the fact that MFC's, unlike chemical fuel cells, must operate at neutral pH in the anode chamber to ensure optimum growth and activity of the microorganisms catalyzing the reactions. At the cathode, OH- ions cause a local increase in pH, due to a limiting rate of their transport. Further, every unit of pH increase at the cathode results in a loss of 59 millivolts of energy -- the authors found that the local cathode pH could easily reach >12, representing a substantial loss.

To attempt to remedy this situation, the group conducted a detailed examination of transport properties at the cathode. An ion exchange binder contained in the cathode usually assists transport of ions to the surrounding electrolyte. Normally, this binder is made from a material called Nafion, which the authors explain is good for transporting positively charged cations like protons, but a poor conductor of negatively charged anions like the hydroxide ions that accumulate at the MFC cathode, or anionic buffer species, such as phosphates and bicarbonates, that help transport OH- ions.

An experimental polymer known as AS-4, which has high anion-exchange capacity, was substituted for Nafion as a cathode binder in the study. The modification ensured the efficient transport of hydroxide ions and improved the performance of the cathode. The study showed that OH- transport could be further enhanced by adjusting pH directly, though the addition of CO2 mixed with air as a buffer for the cathode catalyst.

The study represents the first comprehensive analysis of cathode limitations in MFC's and will further the development of these systems through refinement of materials and operating conditions. "The main importance of our study is not to provide immediate answers, but to conduct a mechanistic study to determine how the cathode operates and identify the sources of inefficiency," Torres explains. "Now we can begin to work on solutions."

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Story Source:

The above story is reprinted from materials provided by Arizona State University.

Note: Materials may be edited for content and length. For further information, please contact the source cited above.


Journal Reference:

  1. Sudeep C. Popat, Dongwon Ki, Bruce E. Rittmann, C?sar I. Torres. Importance of OH? Transport from Cathodes in Microbial Fuel Cells. ChemSusChem, 2012; 5 (6): 1071 DOI: 10.1002/cssc.201100777

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

Source: http://www.sciencedaily.com/releases/2012/07/120710133100.htm

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Tuesday, July 10, 2012

Levi's 2Q profit falls 38 percent

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Source: http://news.yahoo.com/levis-2q-profit-falls-38-percent-205738829--finance.html

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Monday, July 9, 2012

Arsenic-Friendly Microbe Now Seems Unlikely

The Associated Press (as carried by the Washington Post) reports that the controversial report of arsenic-based life-forms in a California lake (much hyped by NASA) look suddenly less controversial, but in a way that will disappoint those who hoped that such an unexpected thing had actually been found on earth. Instead, the journal Science "released two papers that rip apart the original research. They 'clearly show' that the bacteria can?t use arsenic as the researchers claimed, said an accompanying statement from the journal." USA Today's version of the story points out that the claim, and subsequent considered rejection of that claim as unsupportable "looks like a case study in how science corrects its mistakes."

Source: http://rss.slashdot.org/~r/Slashdot/slashdotScience/~3/A_ErzQ_cW2g/arsenic-friendly-microbe-now-seems-unlikely

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Samsung dodges U.K. sales ban, Galaxy Tab 10.1 ?not as cool? as iPad

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Source: http://news.yahoo.com/samsung-dodges-u-k-sales-ban-galaxy-tab-133540145.html

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Mickey Mouse takes NKorean stage in show for Kim

In this image made off North Korea's KRT video footage, North Korea's new Moranbong band and performers dressed as America's cartoon characters perform in Pyongyang, North Korea, Friday, July 6, 2012. Mickey Mouse and Winnie the Pooh took the stage for new leader Kim Jong Un, in an unusual performance featuring Disney characters in North Korea. (AP Photo/KRT)

In this image made off North Korea's KRT video footage, North Korea's new Moranbong band and performers dressed as America's cartoon characters perform in Pyongyang, North Korea, Friday, July 6, 2012. Mickey Mouse and Winnie the Pooh took the stage for new leader Kim Jong Un, in an unusual performance featuring Disney characters in North Korea. (AP Photo/KRT)

In this image made off North Korea's KRT video footage, North Korea's new Moranbong band and performers dressed as America's cartoon characters perform in Pyongyang, North Korea, Friday, July 6, 2012. Mickey Mouse and Winnie the Pooh took the stage for new leader Kim Jong Un, in an unusual performance featuring Disney characters in North Korea. (AP Photo/KRT)

In this image made off North Korea's KRT video footage, North Korean leader Kim Jong Un, second from right, watches performances by North Korea's new Moranbong band in Pyongyang, North Korea, Friday, July 6, 2012. Mickey Mouse and Winnie the Pooh took the stage during the concert for Kim in an unusual performance featuring Disney characters in North Korea. (AP Photo/KRT)

North Koreans bow in front of a statue of Kim Il Sung on the 18th anniversary of the late North Korea founder's death on Sunday, July 8, 2012, at Mansu Hill in Pyongyang, North Korea. (AP Photo/Kim Kwang Hyon)

North Koreans visit the statues of late leaders Kim Il Sung, left, and Kim Jong Il, right, on Sunday, July 8, 2012, on Mansu Hill in Pyongyang, North Korea, to pay tribute to Kim Il Sung on the 18th anniversary of the former North Korean leader's death. (AP Photo/Kim Kwang Hyon)

PYONGYANG, North Korea (AP) ? Mickey Mouse and Winnie the Pooh took the stage in North Korea during a concert for new leader Kim Jong Un, in an unusual performance featuring Disney characters.

Performers dressed as Minnie Mouse, Tigger and others danced and pranced as footage from "Snow White," ''Dumbo," ''Beauty and the Beast" and other Disney movies played on a massive backdrop, according to still photos shown on state TV.

The inclusion of characters popular in the West ? particularly from the United States, North Korea's wartime enemy ? is a notable change in direction for performances in Pyongyang. Actors and actresses also showed off new wardrobes, including strapless gowns and little black dresses.

In recent years, performances such as the "Arirang" mass games featured performers dressed as panda bears in homage to North Korean ally China.

This appears to be the first time Disney characters have been included in a major performance, though Winnie the Pooh and Mickey Mouse have been popular among children for several years. Backpacks, pencil cases and pajamas imported from China often feature Disney characters, and stories such as "Dumbo" have been translated into Korean for North Korean schoolchildren. However, it is unusual to make such images a central part of a North Korean performance and to publicize it on state TV.

Zenia Mucha, chief spokesperson for The Walt Disney Co., said the use of Disney characters in the North Korean performance was not authorized by the U.S. entertainment company.

"This was not licensed or authorized by The Walt Disney Company," Mucha told the AP by telephone on Sunday.

U.S. sanctions prohibit the import of North Korean goods to the United States, but do not ban the sales of American consumer products in North Korea unless they involve officials or companies on the U.S. Treasury Department's sanctions blacklist.

The performance was staged Friday by the Moranbong band, which was making its debut after being assembled by Kim himself, the state-run Korean Central News Agency said.

Kim, who took power after his father, longtime leader Kim Jong Il, died in December, has a "grandiose plan to bring about a dramatic turn in the field of literature and arts this year," KCNA said.

The dispatch made no mention of Disney characters, but said the concert included the traditional folk tune "Arirang" as well as a number of upbeat foreign songs.

Featuring Disney characters signals that Kim may be seeking to carve out a different image than his father and grandfather by easing restrictions on Western culture, said Koh Yu-hwan, a North Korean studies professor based in Seoul, South Korea.

Kim, who is in his late 20s, has sought to project an image of youth, vitality and modernity.

Early Sunday, he led top officials in paying their respects to his grandfather, North Korea founder Kim Il Sung, at the mausoleum where he lies in state. Kim died 18 years ago Sunday.

Earlier in the year, a quintet of accordionists became a YouTube sensation for their arrangement of "Take on Me," a pop song by the Norwegian band a-ha.

North Korea and the United States remain in a technical state of war because they signed a truce, not a peace treaty, after three years of fighting in 1953. The foes do not have diplomatic relations.

___

Associated Press writers Jean H. Lee and Hyung-jin Kim in Seoul, South Korea, contributed to this report.

Associated Press

Source: http://hosted2.ap.org/APDEFAULT/3d281c11a96b4ad082fe88aa0db04305/Article_2012-07-08-NKorea-Disney%20Characters/id-7643006b8dfe4ad39a5d4db3644eab85

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